Enhanced Catalytic Performance by Zirconium Phosphate-Modified SiO2-Supported Ru, Co Catalyst for Fischer-Tropsch Synthesis

Jong Wook Bae; Seon Ju Park; Min Hee Woo; Joo Young Cheon; Kyoung Su Ha; Ki Won Jun; Dong Hyun Lee; Hyun Min Jung

doi:10.1002/cctc.201100102

Enhanced Catalytic Performance by Zirconium Phosphate-Modified SiO₂-Supported Ru, Co Catalyst for Fischer-Tropsch Synthesis

Jong Wook Bae
, Seon Ju Park
, Min Hee Woo
, Joo Young Cheon
, Kyoung Su Ha
, Ki Won Jun
, Dong Hyun Lee
, Hyun Min Jung

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Our zirconium phosphate (ZrP)-promoted Ru/Co/ZrP/SiO₂ catalyst reveals a high catalytic activity and stability during Fischer-Tropsch synthesis. Surface modification with ZrP on SiO₂ support with an appropriate amount of phosphorous component prevents cobalt particle aggregation and enhances its stability. These positive effects of ZrP are mainly induced by the spatial confinement of cobalt particles in a thermally stable ZrP matrix, and the catalytic performance was greatly improved when the P/(Zr+P) molar ratio was 0.134 on the CoZrP(0.5) catalyst.

Original language	English
Pages (from-to)	1342-1347
Number of pages	6
Journal	ChemCatChem
Volume	3
Issue number	8
DOIs	https://doi.org/10.1002/cctc.201100102
State	Published - 8 Aug 2011

Keywords

Aggregation
Cobalt
Fischer-Tropsch synthesis
Matrix
Spatial confinement

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10.1002/cctc.201100102

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title = "Enhanced Catalytic Performance by Zirconium Phosphate-Modified SiO2-Supported Ru, Co Catalyst for Fischer-Tropsch Synthesis",

abstract = "Our zirconium phosphate (ZrP)-promoted Ru/Co/ZrP/SiO2 catalyst reveals a high catalytic activity and stability during Fischer-Tropsch synthesis. Surface modification with ZrP on SiO2 support with an appropriate amount of phosphorous component prevents cobalt particle aggregation and enhances its stability. These positive effects of ZrP are mainly induced by the spatial confinement of cobalt particles in a thermally stable ZrP matrix, and the catalytic performance was greatly improved when the P/(Zr+P) molar ratio was 0.134 on the CoZrP(0.5) catalyst.",

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year = "2011",

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doi = "10.1002/cctc.201100102",

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T1 - Enhanced Catalytic Performance by Zirconium Phosphate-Modified SiO2-Supported Ru, Co Catalyst for Fischer-Tropsch Synthesis

AU - Bae, Jong Wook

AU - Park, Seon Ju

AU - Woo, Min Hee

AU - Cheon, Joo Young

AU - Ha, Kyoung Su

AU - Jun, Ki Won

AU - Lee, Dong Hyun

AU - Jung, Hyun Min

PY - 2011/8/8

Y1 - 2011/8/8

N2 - Our zirconium phosphate (ZrP)-promoted Ru/Co/ZrP/SiO2 catalyst reveals a high catalytic activity and stability during Fischer-Tropsch synthesis. Surface modification with ZrP on SiO2 support with an appropriate amount of phosphorous component prevents cobalt particle aggregation and enhances its stability. These positive effects of ZrP are mainly induced by the spatial confinement of cobalt particles in a thermally stable ZrP matrix, and the catalytic performance was greatly improved when the P/(Zr+P) molar ratio was 0.134 on the CoZrP(0.5) catalyst.

AB - Our zirconium phosphate (ZrP)-promoted Ru/Co/ZrP/SiO2 catalyst reveals a high catalytic activity and stability during Fischer-Tropsch synthesis. Surface modification with ZrP on SiO2 support with an appropriate amount of phosphorous component prevents cobalt particle aggregation and enhances its stability. These positive effects of ZrP are mainly induced by the spatial confinement of cobalt particles in a thermally stable ZrP matrix, and the catalytic performance was greatly improved when the P/(Zr+P) molar ratio was 0.134 on the CoZrP(0.5) catalyst.

KW - Aggregation

KW - Cobalt

KW - Fischer-Tropsch synthesis

KW - Matrix

KW - Spatial confinement

UR - https://www.scopus.com/pages/publications/80051826779

U2 - 10.1002/cctc.201100102

DO - 10.1002/cctc.201100102

M3 - Article

AN - SCOPUS:80051826779

SN - 1867-3880

VL - 3

SP - 1342

EP - 1347

JO - ChemCatChem

JF - ChemCatChem

IS - 8

ER -

Enhanced Catalytic Performance by Zirconium Phosphate-Modified SiO₂-Supported Ru, Co Catalyst for Fischer-Tropsch Synthesis

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Keywords

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