TY - JOUR
T1 - Electrochemical synthesis of single-crystal (Ba0.05K0.95)BiO3·1/6H2O with the KSbO3 structure
AU - Jung, D. Y.
AU - Han, P.
AU - Wilson, S. R.
AU - Payne, D. A.
PY - 1998
Y1 - 1998
N2 - A new compound with a cubic structure, (Ba0.05K0.95)BiO3·1/6H2O (BKBO), was synthesized by electrochemical crystal growth using a rotating anode in molten KOH flux at 255°C. The BKBO crystal had the KSbO3 structure and belonged to space group Im3 (No. 204) with Z = 12. Refinement of X-ray diffraction data at room temperature gave a = 10.0204(2) Å, V = 1006.1(1) Å3, and R = 2.4% for 1465 unique reflections. Potassium, barium, and hydrated oxygen were found to occupy different sites in the tunnel structure. The electrical conductivity at room temperature was similar to the ionic conductor KBiO3. BKBO decomposed to Bi2O3, K2O, and BaO above 400°C.
AB - A new compound with a cubic structure, (Ba0.05K0.95)BiO3·1/6H2O (BKBO), was synthesized by electrochemical crystal growth using a rotating anode in molten KOH flux at 255°C. The BKBO crystal had the KSbO3 structure and belonged to space group Im3 (No. 204) with Z = 12. Refinement of X-ray diffraction data at room temperature gave a = 10.0204(2) Å, V = 1006.1(1) Å3, and R = 2.4% for 1465 unique reflections. Potassium, barium, and hydrated oxygen were found to occupy different sites in the tunnel structure. The electrical conductivity at room temperature was similar to the ionic conductor KBiO3. BKBO decomposed to Bi2O3, K2O, and BaO above 400°C.
KW - A. oxides
KW - B. crystal growth
KW - C. X-ray diffraction
KW - D. crystal structure
UR - https://www.scopus.com/pages/publications/0032132037
U2 - 10.1016/S0025-5408(98)00101-9
DO - 10.1016/S0025-5408(98)00101-9
M3 - Article
AN - SCOPUS:0032132037
SN - 0025-5408
VL - 33
SP - 1195
EP - 1205
JO - Materials Research Bulletin
JF - Materials Research Bulletin
IS - 8
ER -