Effects of promoter and moisture on the deactivation of FSO3H catalyst in the synthesis of HFC-152a by hydrofluorination of acetylene

Young Ho Lee; Jae Duck Kim; Jaehoon Kim; Hwayong Kim; Youn Woo Lee

doi:10.1007/s11814-009-0117-7

Effects of promoter and moisture on the deactivation of FSO₃H catalyst in the synthesis of HFC-152a by hydrofluorination of acetylene

Young Ho Lee
, Jae Duck Kim
, Jaehoon Kim
, Hwayong Kim
, Youn Woo Lee

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The effects of promoter type and moisture on the catalytic activity of fluorosulfonic acid (FSO₃H) as a liquid catalyst for the synthesis of HFC-152a by the hydrofluorination of acetylene were investigated. The catalyst containing SnCl₄ as a promoter had a long catalyst lifetime compared to that without any promoter. It was also found that the composition of HFC-152a can be maintained at 100% for a long time by the control of the moisture content.

Original language	English
Pages (from-to)	702-704
Number of pages	3
Journal	Korean Journal of Chemical Engineering
Volume	26
Issue number	3
DOIs	https://doi.org/10.1007/s11814-009-0117-7
State	Published - May 2009
Externally published	Yes

Keywords

Acetylene
Additives
HFC-152a
Hydrofluorination
Liquid FSOH Catalyst

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10.1007/s11814-009-0117-7

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title = "Effects of promoter and moisture on the deactivation of FSO3H catalyst in the synthesis of HFC-152a by hydrofluorination of acetylene",

abstract = "The effects of promoter type and moisture on the catalytic activity of fluorosulfonic acid (FSO3H) as a liquid catalyst for the synthesis of HFC-152a by the hydrofluorination of acetylene were investigated. The catalyst containing SnCl4 as a promoter had a long catalyst lifetime compared to that without any promoter. It was also found that the composition of HFC-152a can be maintained at 100\% for a long time by the control of the moisture content.",

keywords = "Acetylene, Additives, HFC-152a, Hydrofluorination, Liquid FSOH Catalyst",

author = "Lee, \{Young Ho\} and Kim, \{Jae Duck\} and Jaehoon Kim and Hwayong Kim and Lee, \{Youn Woo\}",

year = "2009",

month = may,

doi = "10.1007/s11814-009-0117-7",

language = "English",

volume = "26",

pages = "702--704",

journal = "Korean Journal of Chemical Engineering",

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T1 - Effects of promoter and moisture on the deactivation of FSO3H catalyst in the synthesis of HFC-152a by hydrofluorination of acetylene

AU - Lee, Young Ho

AU - Kim, Jae Duck

AU - Kim, Jaehoon

AU - Kim, Hwayong

AU - Lee, Youn Woo

PY - 2009/5

Y1 - 2009/5

N2 - The effects of promoter type and moisture on the catalytic activity of fluorosulfonic acid (FSO3H) as a liquid catalyst for the synthesis of HFC-152a by the hydrofluorination of acetylene were investigated. The catalyst containing SnCl4 as a promoter had a long catalyst lifetime compared to that without any promoter. It was also found that the composition of HFC-152a can be maintained at 100% for a long time by the control of the moisture content.

AB - The effects of promoter type and moisture on the catalytic activity of fluorosulfonic acid (FSO3H) as a liquid catalyst for the synthesis of HFC-152a by the hydrofluorination of acetylene were investigated. The catalyst containing SnCl4 as a promoter had a long catalyst lifetime compared to that without any promoter. It was also found that the composition of HFC-152a can be maintained at 100% for a long time by the control of the moisture content.

KW - Acetylene

KW - Additives

KW - HFC-152a

KW - Hydrofluorination

KW - Liquid FSOH Catalyst

UR - https://www.scopus.com/pages/publications/65949090951

U2 - 10.1007/s11814-009-0117-7

DO - 10.1007/s11814-009-0117-7

M3 - Article

AN - SCOPUS:65949090951

SN - 0256-1115

VL - 26

SP - 702

EP - 704

JO - Korean Journal of Chemical Engineering

JF - Korean Journal of Chemical Engineering

IS - 3

ER -

Effects of promoter and moisture on the deactivation of FSO₃H catalyst in the synthesis of HFC-152a by hydrofluorination of acetylene

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Keywords

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