Effect of calcination temperature on the association between free NiO species and catalytic activity of Ni−Ce0.6Zr0.4O2 deoxygenation catalysts for biodiesel production

Kyung Won Jeon; Jae Oh Shim; Won Jun Jang; Da We Lee; Hyun Suk Na; Hak Min Kim; Yeol Lim Lee; Seong Yeun Yoo; Hyun Seog Roh; Byong Hun Jeon; Jong Wook Bae; Chang Hyun Ko

doi:10.1016/j.renene.2018.07.042

Effect of calcination temperature on the association between free NiO species and catalytic activity of Ni−Ce_0.6Zr_0.4O₂ deoxygenation catalysts for biodiesel production

Kyung Won Jeon, Jae Oh Shim, Won Jun Jang, Da We Lee, Hyun Suk Na, Hak Min Kim, Yeol Lim Lee, Seong Yeun Yoo, Hyun Seog Roh, Byong Hun Jeon, Jong Wook Bae, Chang Hyun Ko

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

In this study, a series of Ni−Ce_0.6Zr_0.4O₂ catalysts, which were synthesized by co-precipitation followed by calcination at different temperatures, were applied for the deoxygenation of oleic acid. The physicochemical properties of the catalysts were characterized by N₂ adsorption-desorption, X-ray diffraction (XRD), H₂ chemisorption, H₂ temperature-programmed reduction (H₂-TPR), NH₃ temperature-programmed desorption (NH₃-TPD), and X-ray photoelectron spectroscopy (XPS). The Ni−Ce_0.6Zr_0.4O₂ catalyst calcined at 300 °C exhibited the highest conversion for oleic acid as well as selectivity for diesel-range compounds. It is predominantly related to the highest amount of free NiO species. In addition, the acidity of the catalyst significantly affected the selectivity and distribution of products.

Original language	English
Pages (from-to)	144-151
Number of pages	8
Journal	Renewable Energy
Volume	131
DOIs	https://doi.org/10.1016/j.renene.2018.07.042
State	Published - Feb 2019

Keywords

Acidity
Calcination temperature
Deoxygenation
Free NiO
Oleic acid

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.renene.2018.07.042

Cite this

Jeon, K. W., Shim, J. O., Jang, W. J., Lee, D. W., Na, H. S., Kim, H. M., Lee, Y. L., Yoo, S. Y., Roh, H. S., Jeon, B. H., Bae, J. W., & Ko, C. H. (2019). Effect of calcination temperature on the association between free NiO species and catalytic activity of Ni−Ce_0.6Zr_0.4O₂ deoxygenation catalysts for biodiesel production. Renewable Energy, 131, 144-151. https://doi.org/10.1016/j.renene.2018.07.042

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title = "Effect of calcination temperature on the association between free NiO species and catalytic activity of Ni−Ce0.6Zr0.4O2 deoxygenation catalysts for biodiesel production",

abstract = "In this study, a series of Ni−Ce0.6Zr0.4O2 catalysts, which were synthesized by co-precipitation followed by calcination at different temperatures, were applied for the deoxygenation of oleic acid. The physicochemical properties of the catalysts were characterized by N2 adsorption-desorption, X-ray diffraction (XRD), H2 chemisorption, H2 temperature-programmed reduction (H2-TPR), NH3 temperature-programmed desorption (NH3-TPD), and X-ray photoelectron spectroscopy (XPS). The Ni−Ce0.6Zr0.4O2 catalyst calcined at 300 °C exhibited the highest conversion for oleic acid as well as selectivity for diesel-range compounds. It is predominantly related to the highest amount of free NiO species. In addition, the acidity of the catalyst significantly affected the selectivity and distribution of products.",

keywords = "Acidity, Calcination temperature, Deoxygenation, Free NiO, Oleic acid",

author = "Jeon, \{Kyung Won\} and Shim, \{Jae Oh\} and Jang, \{Won Jun\} and Lee, \{Da We\} and Na, \{Hyun Suk\} and Kim, \{Hak Min\} and Lee, \{Yeol Lim\} and Yoo, \{Seong Yeun\} and Roh, \{Hyun Seog\} and Jeon, \{Byong Hun\} and Bae, \{Jong Wook\} and Ko, \{Chang Hyun\}",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier Ltd",

year = "2019",

month = feb,

doi = "10.1016/j.renene.2018.07.042",

language = "English",

volume = "131",

pages = "144--151",

journal = "Renewable Energy",

issn = "0960-1481",

publisher = "Elsevier Ltd",

}

Jeon, KW, Shim, JO, Jang, WJ, Lee, DW, Na, HS, Kim, HM, Lee, YL, Yoo, SY, Roh, HS, Jeon, BH, Bae, JW & Ko, CH 2019, 'Effect of calcination temperature on the association between free NiO species and catalytic activity of Ni−Ce_0.6Zr_0.4O₂ deoxygenation catalysts for biodiesel production', Renewable Energy, vol. 131, pp. 144-151. https://doi.org/10.1016/j.renene.2018.07.042

TY - JOUR

T1 - Effect of calcination temperature on the association between free NiO species and catalytic activity of Ni−Ce0.6Zr0.4O2 deoxygenation catalysts for biodiesel production

AU - Jeon, Kyung Won

AU - Shim, Jae Oh

AU - Jang, Won Jun

AU - Lee, Da We

AU - Na, Hyun Suk

AU - Kim, Hak Min

AU - Lee, Yeol Lim

AU - Yoo, Seong Yeun

AU - Roh, Hyun Seog

AU - Jeon, Byong Hun

AU - Bae, Jong Wook

AU - Ko, Chang Hyun

PY - 2019/2

Y1 - 2019/2

N2 - In this study, a series of Ni−Ce0.6Zr0.4O2 catalysts, which were synthesized by co-precipitation followed by calcination at different temperatures, were applied for the deoxygenation of oleic acid. The physicochemical properties of the catalysts were characterized by N2 adsorption-desorption, X-ray diffraction (XRD), H2 chemisorption, H2 temperature-programmed reduction (H2-TPR), NH3 temperature-programmed desorption (NH3-TPD), and X-ray photoelectron spectroscopy (XPS). The Ni−Ce0.6Zr0.4O2 catalyst calcined at 300 °C exhibited the highest conversion for oleic acid as well as selectivity for diesel-range compounds. It is predominantly related to the highest amount of free NiO species. In addition, the acidity of the catalyst significantly affected the selectivity and distribution of products.

AB - In this study, a series of Ni−Ce0.6Zr0.4O2 catalysts, which were synthesized by co-precipitation followed by calcination at different temperatures, were applied for the deoxygenation of oleic acid. The physicochemical properties of the catalysts were characterized by N2 adsorption-desorption, X-ray diffraction (XRD), H2 chemisorption, H2 temperature-programmed reduction (H2-TPR), NH3 temperature-programmed desorption (NH3-TPD), and X-ray photoelectron spectroscopy (XPS). The Ni−Ce0.6Zr0.4O2 catalyst calcined at 300 °C exhibited the highest conversion for oleic acid as well as selectivity for diesel-range compounds. It is predominantly related to the highest amount of free NiO species. In addition, the acidity of the catalyst significantly affected the selectivity and distribution of products.

KW - Acidity

KW - Calcination temperature

KW - Deoxygenation

KW - Free NiO

KW - Oleic acid

UR - https://www.scopus.com/pages/publications/85052320687

U2 - 10.1016/j.renene.2018.07.042

DO - 10.1016/j.renene.2018.07.042

M3 - Article

AN - SCOPUS:85052320687

SN - 0960-1481

VL - 131

SP - 144

EP - 151

JO - Renewable Energy

JF - Renewable Energy

ER -