Dual role of Cu2O nanocubes as templates and networking catalysts for hollow and microporous Fe-porphyrin networks

Daye Kang; Ju Hong Ko; Jaewon Choi; Kyoungil Cho; Sang Moon Lee; Hae Jin Kim; Yoon Joo Ko; Kang Hyun Park; Seung Uk Son

doi:10.1039/c6cc10005h

Dual role of Cu₂O nanocubes as templates and networking catalysts for hollow and microporous Fe-porphyrin networks

Daye Kang
, Ju Hong Ko
, Jaewon Choi
, Kyoungil Cho
, Sang Moon Lee
, Hae Jin Kim
, Yoon Joo Ko
, Kang Hyun Park
, Seung Uk Son

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Cu₂O nanocubes were used for the synthesis of hollow and microporous Fe porphyrin networks (H-MFePN). In this synthesis, Cu₂O nanocubes performed not only as networking catalysts but also as shape controlling templates. MFePN were formed on the surface of the Cu₂O nanocubes through azide-alkyne cycloaddition of tetrakis(4-ethynylphenyl) Fe-porphyrin with 1,4-diazidobenzene. H-MFePN showed excellent catalytic activities in carbene insertion into N-H bonds, maintaining their activities during five recycle tests.

Original language	English
Pages (from-to)	2598-2601
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	17
DOIs	https://doi.org/10.1039/c6cc10005h
State	Published - 2017

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title = "Dual role of Cu2O nanocubes as templates and networking catalysts for hollow and microporous Fe-porphyrin networks",

abstract = "Cu2O nanocubes were used for the synthesis of hollow and microporous Fe porphyrin networks (H-MFePN). In this synthesis, Cu2O nanocubes performed not only as networking catalysts but also as shape controlling templates. MFePN were formed on the surface of the Cu2O nanocubes through azide-alkyne cycloaddition of tetrakis(4-ethynylphenyl) Fe-porphyrin with 1,4-diazidobenzene. H-MFePN showed excellent catalytic activities in carbene insertion into N-H bonds, maintaining their activities during five recycle tests.",

author = "Daye Kang and Ko, \{Ju Hong\} and Jaewon Choi and Kyoungil Cho and Lee, \{Sang Moon\} and Kim, \{Hae Jin\} and Ko, \{Yoon Joo\} and Park, \{Kang Hyun\} and Son, \{Seung Uk\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c6cc10005h",

language = "English",

volume = "53",

pages = "2598--2601",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Dual role of Cu2O nanocubes as templates and networking catalysts for hollow and microporous Fe-porphyrin networks

AU - Kang, Daye

AU - Ko, Ju Hong

AU - Choi, Jaewon

AU - Cho, Kyoungil

AU - Lee, Sang Moon

AU - Kim, Hae Jin

AU - Ko, Yoon Joo

AU - Park, Kang Hyun

AU - Son, Seung Uk

PY - 2017

Y1 - 2017

N2 - Cu2O nanocubes were used for the synthesis of hollow and microporous Fe porphyrin networks (H-MFePN). In this synthesis, Cu2O nanocubes performed not only as networking catalysts but also as shape controlling templates. MFePN were formed on the surface of the Cu2O nanocubes through azide-alkyne cycloaddition of tetrakis(4-ethynylphenyl) Fe-porphyrin with 1,4-diazidobenzene. H-MFePN showed excellent catalytic activities in carbene insertion into N-H bonds, maintaining their activities during five recycle tests.

AB - Cu2O nanocubes were used for the synthesis of hollow and microporous Fe porphyrin networks (H-MFePN). In this synthesis, Cu2O nanocubes performed not only as networking catalysts but also as shape controlling templates. MFePN were formed on the surface of the Cu2O nanocubes through azide-alkyne cycloaddition of tetrakis(4-ethynylphenyl) Fe-porphyrin with 1,4-diazidobenzene. H-MFePN showed excellent catalytic activities in carbene insertion into N-H bonds, maintaining their activities during five recycle tests.

UR - https://www.scopus.com/pages/publications/85013894245

U2 - 10.1039/c6cc10005h

DO - 10.1039/c6cc10005h

M3 - Article

C2 - 28191560

AN - SCOPUS:85013894245

SN - 1359-7345

VL - 53

SP - 2598

EP - 2601

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Dual role of Cu₂O nanocubes as templates and networking catalysts for hollow and microporous Fe-porphyrin networks

Abstract

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