Diels-Alder cycloaddition of cyclopentadiene with ethylacrylate catalyzed by mesoporous Al-MCM-48 and Al-MCM-41 catalysts

Jeong Kuk Shon; Jae Yi Sim; Santosh Singh Thakur; Eun Mi Ko; Soo Sung Kong; Ji Yun Choi; Min Kang; Bidyut Kumar Senapati; Doo Seoung Choi; Do Hyun Ryu; Ji Man Kim

doi:10.5012/bkcs.2008.29.10.1993

Diels-Alder cycloaddition of cyclopentadiene with ethylacrylate catalyzed by mesoporous Al-MCM-48 and Al-MCM-41 catalysts

Jeong Kuk Shon, Jae Yi Sim, Santosh Singh Thakur, Eun Mi Ko, Soo Sung Kong, Ji Yun Choi, Min Kang, Bidyut Kumar Senapati, Doo Seoung Choi, Do Hyun Ryu, Ji Man Kim

Department of Chemistry

Sungkyunkwan University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

In the present work, Diels-Alder reaction of cyclopentadiene with ethylacrylate has been carried out by using two types of mesoporous solid acid catalysts (Al-MCM-41, Al-MCM-48) with different pore structures. The specific topology of Al-MCM-48 (cubic Ia3d structure composed of two independent 3-D channel systems) exhibit higher activity and stereo-control than those of Al-MCM-41 (hexagonal packing of 1-D channels). The physical properties of Al-MCM-48 catalyst, such as high accessibility of reactants to the acid sites, spatial confinement in the nanoscopic reactors, and 3-D channel network structure that are effective adsorption and diffusion of reactants, play a crucial role in the present study.

Original language	English
Pages (from-to)	1993-1997
Number of pages	5
Journal	Bulletin of the Korean Chemical Society
Volume	29
Issue number	10
DOIs	https://doi.org/10.5012/bkcs.2008.29.10.1993
State	Published - 20 Oct 2008

Keywords

Al-MCM-48
Cyclopentadiene
Diels-Alder reaction
Ethylacrylate
Mesoporous catalyst

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10.5012/bkcs.2008.29.10.1993

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Shon, J. K., Sim, J. Y., Thakur, S. S., Ko, E. M., Kong, S. S., Choi, J. Y., Kang, M., Senapati, B. K., Choi, D. S., Ryu, D. H., & Kim, J. M. (2008). Diels-Alder cycloaddition of cyclopentadiene with ethylacrylate catalyzed by mesoporous Al-MCM-48 and Al-MCM-41 catalysts. Bulletin of the Korean Chemical Society, 29(10), 1993-1997. https://doi.org/10.5012/bkcs.2008.29.10.1993

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title = "Diels-Alder cycloaddition of cyclopentadiene with ethylacrylate catalyzed by mesoporous Al-MCM-48 and Al-MCM-41 catalysts",

abstract = "In the present work, Diels-Alder reaction of cyclopentadiene with ethylacrylate has been carried out by using two types of mesoporous solid acid catalysts (Al-MCM-41, Al-MCM-48) with different pore structures. The specific topology of Al-MCM-48 (cubic Ia3d structure composed of two independent 3-D channel systems) exhibit higher activity and stereo-control than those of Al-MCM-41 (hexagonal packing of 1-D channels). The physical properties of Al-MCM-48 catalyst, such as high accessibility of reactants to the acid sites, spatial confinement in the nanoscopic reactors, and 3-D channel network structure that are effective adsorption and diffusion of reactants, play a crucial role in the present study.",

keywords = "Al-MCM-48, Cyclopentadiene, Diels-Alder reaction, Ethylacrylate, Mesoporous catalyst",

author = "Shon, \{Jeong Kuk\} and Sim, \{Jae Yi\} and Thakur, \{Santosh Singh\} and Ko, \{Eun Mi\} and Kong, \{Soo Sung\} and Choi, \{Ji Yun\} and Min Kang and Senapati, \{Bidyut Kumar\} and Choi, \{Doo Seoung\} and Ryu, \{Do Hyun\} and Kim, \{Ji Man\}",

year = "2008",

month = oct,

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doi = "10.5012/bkcs.2008.29.10.1993",

language = "English",

volume = "29",

pages = "1993--1997",

journal = "Bulletin of the Korean Chemical Society",

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TY - JOUR

T1 - Diels-Alder cycloaddition of cyclopentadiene with ethylacrylate catalyzed by mesoporous Al-MCM-48 and Al-MCM-41 catalysts

AU - Shon, Jeong Kuk

AU - Sim, Jae Yi

AU - Thakur, Santosh Singh

AU - Ko, Eun Mi

AU - Kong, Soo Sung

AU - Choi, Ji Yun

AU - Kang, Min

AU - Senapati, Bidyut Kumar

AU - Choi, Doo Seoung

AU - Ryu, Do Hyun

AU - Kim, Ji Man

PY - 2008/10/20

Y1 - 2008/10/20

N2 - In the present work, Diels-Alder reaction of cyclopentadiene with ethylacrylate has been carried out by using two types of mesoporous solid acid catalysts (Al-MCM-41, Al-MCM-48) with different pore structures. The specific topology of Al-MCM-48 (cubic Ia3d structure composed of two independent 3-D channel systems) exhibit higher activity and stereo-control than those of Al-MCM-41 (hexagonal packing of 1-D channels). The physical properties of Al-MCM-48 catalyst, such as high accessibility of reactants to the acid sites, spatial confinement in the nanoscopic reactors, and 3-D channel network structure that are effective adsorption and diffusion of reactants, play a crucial role in the present study.

AB - In the present work, Diels-Alder reaction of cyclopentadiene with ethylacrylate has been carried out by using two types of mesoporous solid acid catalysts (Al-MCM-41, Al-MCM-48) with different pore structures. The specific topology of Al-MCM-48 (cubic Ia3d structure composed of two independent 3-D channel systems) exhibit higher activity and stereo-control than those of Al-MCM-41 (hexagonal packing of 1-D channels). The physical properties of Al-MCM-48 catalyst, such as high accessibility of reactants to the acid sites, spatial confinement in the nanoscopic reactors, and 3-D channel network structure that are effective adsorption and diffusion of reactants, play a crucial role in the present study.

KW - Al-MCM-48

KW - Cyclopentadiene

KW - Diels-Alder reaction

KW - Ethylacrylate

KW - Mesoporous catalyst

UR - https://www.scopus.com/pages/publications/55249092082

U2 - 10.5012/bkcs.2008.29.10.1993

DO - 10.5012/bkcs.2008.29.10.1993

M3 - Article

AN - SCOPUS:55249092082

SN - 0253-2964

VL - 29

SP - 1993

EP - 1997

JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

IS - 10

ER -

Diels-Alder cycloaddition of cyclopentadiene with ethylacrylate catalyzed by mesoporous Al-MCM-48 and Al-MCM-41 catalysts

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Keywords

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