Diaquatetrakis(pyrazine-2-carboxylato-κ2O,N)-thorium(IV) trihydrate

Thattan Premkumar; Subbiah Govindarajan; Wojciech Starosta; Janusz Leciejewicz

doi:10.1107/S1600536805039346

Diaquatetrakis(pyrazine-2-carboxylato-κ²O,N)-thorium(IV) trihydrate

Thattan Premkumar
, Subbiah Govindarajan
, Wojciech Starosta
, Janusz Leciejewicz

Bharathiar University
Institute of Nuclear Chemistry and Technology, Warsaw

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The structure of the title compound, [Th(C₅H₃N ₂O₂)₄-(H₂O)₂· 3H₂O, contains monomeric molecules composed of a thorium(IV) ion coordinated by N,O-chelating groups donated by four pyrazine-2-carboxylate ligands [mean Th N = 2.773 (30) Å and mean Th-O = 2.391 (17) Å] and two water O atoms [mean Th-O = 2.517 (30) Å]. The coordination polyhedron around the Th^IV ion is an irregular hexa-decahedron.

Original language	English
Pages (from-to)	m98-m100
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	1
DOIs	https://doi.org/10.1107/S1600536805039346
State	Published - Jan 2006
Externally published	Yes

Access to Document

10.1107/S1600536805039346

Cite this

@article{16e6a0f59f3c4f008d77a57ce149225c,

title = "Diaquatetrakis(pyrazine-2-carboxylato-κ2O,N)-thorium(IV) trihydrate",

abstract = "The structure of the title compound, [Th(C5H3N 2O2)4-(H2O)2· 3H2O, contains monomeric molecules composed of a thorium(IV) ion coordinated by N,O-chelating groups donated by four pyrazine-2-carboxylate ligands [mean Th N = 2.773 (30) {\AA} and mean Th-O = 2.391 (17) {\AA}] and two water O atoms [mean Th-O = 2.517 (30) {\AA}]. The coordination polyhedron around the ThIV ion is an irregular hexa-decahedron.",

author = "Thattan Premkumar and Subbiah Govindarajan and Wojciech Starosta and Janusz Leciejewicz",

year = "2006",

month = jan,

doi = "10.1107/S1600536805039346",

language = "English",

volume = "62",

pages = "m98--m100",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "1",

}

TY - JOUR

T1 - Diaquatetrakis(pyrazine-2-carboxylato-κ2O,N)-thorium(IV) trihydrate

AU - Premkumar, Thattan

AU - Govindarajan, Subbiah

AU - Starosta, Wojciech

AU - Leciejewicz, Janusz

PY - 2006/1

Y1 - 2006/1

N2 - The structure of the title compound, [Th(C5H3N 2O2)4-(H2O)2· 3H2O, contains monomeric molecules composed of a thorium(IV) ion coordinated by N,O-chelating groups donated by four pyrazine-2-carboxylate ligands [mean Th N = 2.773 (30) Å and mean Th-O = 2.391 (17) Å] and two water O atoms [mean Th-O = 2.517 (30) Å]. The coordination polyhedron around the ThIV ion is an irregular hexa-decahedron.

AB - The structure of the title compound, [Th(C5H3N 2O2)4-(H2O)2· 3H2O, contains monomeric molecules composed of a thorium(IV) ion coordinated by N,O-chelating groups donated by four pyrazine-2-carboxylate ligands [mean Th N = 2.773 (30) Å and mean Th-O = 2.391 (17) Å] and two water O atoms [mean Th-O = 2.517 (30) Å]. The coordination polyhedron around the ThIV ion is an irregular hexa-decahedron.

UR - https://www.scopus.com/pages/publications/33644974698

U2 - 10.1107/S1600536805039346

DO - 10.1107/S1600536805039346

M3 - Article

AN - SCOPUS:33644974698

SN - 1600-5368

VL - 62

SP - m98-m100

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 1

ER -

Diaquatetrakis(pyrazine-2-carboxylato-κ²O,N)-thorium(IV) trihydrate

Abstract

Access to Document

Other files and links

Fingerprint

Cite this