Cp*Rh(III)-catalyzed C(sp3)-H alkylation of 8-methylquinolines in aqueous media

Saegun Kim; Sangil Han; Jihye Park; Satyasheel Sharma; Neeraj Kumar Mishra; Hyunjung Oh; Jong Hwan Kwak; In Su Kim

doi:10.1039/c6cc09830d

Cp*Rh(III)-catalyzed C(sp³)-H alkylation of 8-methylquinolines in aqueous media

Saegun Kim
, Sangil Han
, Jihye Park
, Satyasheel Sharma
, Neeraj Kumar Mishra
, Hyunjung Oh
, Jong Hwan Kwak
, In Su Kim

Department of Pharmacy

Sungkyunkwan University

Research output: Contribution to journal › Article › peer-review

73 Scopus citations

Abstract

The rhodium(iii)-catalyzed cross-coupling reaction of 8-methylquinolines with a range of allylic alcohols in water is described. This approach leads to the synthesis of various γ-quinolinyl carbonyl compounds, which are synthetically useful precursors for the construction of bioactive tetrahydroquinoline and azasteroid derivatives.

Original language	English
Pages (from-to)	3006-3009
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	21
DOIs	https://doi.org/10.1039/c6cc09830d
State	Published - 2017

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title = "Cp*Rh(III)-catalyzed C(sp3)-H alkylation of 8-methylquinolines in aqueous media",

abstract = "The rhodium(iii)-catalyzed cross-coupling reaction of 8-methylquinolines with a range of allylic alcohols in water is described. This approach leads to the synthesis of various γ-quinolinyl carbonyl compounds, which are synthetically useful precursors for the construction of bioactive tetrahydroquinoline and azasteroid derivatives.",

author = "Saegun Kim and Sangil Han and Jihye Park and Satyasheel Sharma and Mishra, \{Neeraj Kumar\} and Hyunjung Oh and Kwak, \{Jong Hwan\} and Kim, \{In Su\}",

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year = "2017",

doi = "10.1039/c6cc09830d",

language = "English",

volume = "53",

pages = "3006--3009",

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publisher = "Royal Society of Chemistry",

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T1 - Cp*Rh(III)-catalyzed C(sp3)-H alkylation of 8-methylquinolines in aqueous media

AU - Kim, Saegun

AU - Han, Sangil

AU - Park, Jihye

AU - Sharma, Satyasheel

AU - Mishra, Neeraj Kumar

AU - Oh, Hyunjung

AU - Kwak, Jong Hwan

AU - Kim, In Su

PY - 2017

Y1 - 2017

N2 - The rhodium(iii)-catalyzed cross-coupling reaction of 8-methylquinolines with a range of allylic alcohols in water is described. This approach leads to the synthesis of various γ-quinolinyl carbonyl compounds, which are synthetically useful precursors for the construction of bioactive tetrahydroquinoline and azasteroid derivatives.

AB - The rhodium(iii)-catalyzed cross-coupling reaction of 8-methylquinolines with a range of allylic alcohols in water is described. This approach leads to the synthesis of various γ-quinolinyl carbonyl compounds, which are synthetically useful precursors for the construction of bioactive tetrahydroquinoline and azasteroid derivatives.

UR - https://www.scopus.com/pages/publications/85014993928

U2 - 10.1039/c6cc09830d

DO - 10.1039/c6cc09830d

M3 - Article

C2 - 28184396

AN - SCOPUS:85014993928

SN - 1359-7345

VL - 53

SP - 3006

EP - 3009

JO - Chemical Communications

JF - Chemical Communications

IS - 21

ER -

Cp*Rh(III)-catalyzed C(sp³)-H alkylation of 8-methylquinolines in aqueous media

Abstract

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