Chemoselective and repetitive intermolecular cross-acyloin condensation reactions between a variety of aromatic and aliphatic aldehydes using a robust N-heterocyclic carbene catalyst

Ming Yu Jin; Sun Min Kim; Hui Mao; Do Hyun Ryu; Choong Eui Song; Jung Woon Yang

doi:10.1039/c3ob42486c

Chemoselective and repetitive intermolecular cross-acyloin condensation reactions between a variety of aromatic and aliphatic aldehydes using a robust N-heterocyclic carbene catalyst

Ming Yu Jin
, Sun Min Kim
, Hui Mao
, Do Hyun Ryu
, Choong Eui Song
, Jung Woon Yang

Department of Chemistry

Sungkyunkwan University

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

We found that chemoselectivity of the crossed acyloin product is controlled by the adjustment of the aromatic aldehyde/aliphatic aldehyde ratio. Moreover, we observed the persistent catalytic activity of the homogeneous NHC catalyst in a solution due to NHC catalyst robustness.

Original language	English
Pages (from-to)	1547-1550
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	12
Issue number	10
DOIs	https://doi.org/10.1039/c3ob42486c
State	Published - 14 Mar 2014

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10.1039/c3ob42486c

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title = "Chemoselective and repetitive intermolecular cross-acyloin condensation reactions between a variety of aromatic and aliphatic aldehydes using a robust N-heterocyclic carbene catalyst",

abstract = "We found that chemoselectivity of the crossed acyloin product is controlled by the adjustment of the aromatic aldehyde/aliphatic aldehyde ratio. Moreover, we observed the persistent catalytic activity of the homogeneous NHC catalyst in a solution due to NHC catalyst robustness.",

author = "Jin, \{Ming Yu\} and Kim, \{Sun Min\} and Hui Mao and Ryu, \{Do Hyun\} and Song, \{Choong Eui\} and Yang, \{Jung Woon\}",

year = "2014",

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Chemoselective and repetitive intermolecular cross-acyloin condensation reactions between a variety of aromatic and aliphatic aldehydes using a robust N-heterocyclic carbene catalyst. / Jin, Ming Yu; Kim, Sun Min; Mao, Hui et al.
In: Organic and Biomolecular Chemistry, Vol. 12, No. 10, 14.03.2014, p. 1547-1550.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Chemoselective and repetitive intermolecular cross-acyloin condensation reactions between a variety of aromatic and aliphatic aldehydes using a robust N-heterocyclic carbene catalyst

AU - Jin, Ming Yu

AU - Kim, Sun Min

AU - Mao, Hui

AU - Ryu, Do Hyun

AU - Song, Choong Eui

AU - Yang, Jung Woon

PY - 2014/3/14

Y1 - 2014/3/14

N2 - We found that chemoselectivity of the crossed acyloin product is controlled by the adjustment of the aromatic aldehyde/aliphatic aldehyde ratio. Moreover, we observed the persistent catalytic activity of the homogeneous NHC catalyst in a solution due to NHC catalyst robustness.

AB - We found that chemoselectivity of the crossed acyloin product is controlled by the adjustment of the aromatic aldehyde/aliphatic aldehyde ratio. Moreover, we observed the persistent catalytic activity of the homogeneous NHC catalyst in a solution due to NHC catalyst robustness.

UR - https://www.scopus.com/pages/publications/84893933253

U2 - 10.1039/c3ob42486c

DO - 10.1039/c3ob42486c

M3 - Article

AN - SCOPUS:84893933253

SN - 1477-0520

VL - 12

SP - 1547

EP - 1550

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 10

ER -

Chemoselective and repetitive intermolecular cross-acyloin condensation reactions between a variety of aromatic and aliphatic aldehydes using a robust N-heterocyclic carbene catalyst

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