Asymmetric induction in silyl nitronate cycloadditions to Oppolzer's chiral sultam derivatives

Byeang Hyean Kim; Ju Young Lee; Kimoon Kim; Dongmok Whang

doi:10.1016/S0957-4166(00)82151-5

Asymmetric induction in silyl nitronate cycloadditions to Oppolzer's chiral sultam derivatives

Byeang Hyean Kim
, Ju Young Lee
, Kimoon Kim
, Dongmok Whang

Pohang University of Science and Technology

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

Silyl nitronate cycloadditions to Oppolzer's chiral sultam derivatives, followed by the elimination of the silyl alcohols from the resulting N-silyloxyisoxazolidines, provide Δ₂-isoxazolines in good stereoselectivity (ca. 89/11). The favored transition state is suggested in the light of the X-ray crystal structure of a major cycloadduct.

Original language	English
Pages (from-to)	27-30
Number of pages	4
Journal	Tetrahedron Asymmetry
Volume	2
Issue number	1
DOIs	https://doi.org/10.1016/S0957-4166(00)82151-5
State	Published - 1991
Externally published	Yes

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title = "Asymmetric induction in silyl nitronate cycloadditions to Oppolzer's chiral sultam derivatives",

abstract = "Silyl nitronate cycloadditions to Oppolzer's chiral sultam derivatives, followed by the elimination of the silyl alcohols from the resulting N-silyloxyisoxazolidines, provide Δ2-isoxazolines in good stereoselectivity (ca. 89/11). The favored transition state is suggested in the light of the X-ray crystal structure of a major cycloadduct.",

author = "Kim, \{Byeang Hyean\} and Lee, \{Ju Young\} and Kimoon Kim and Dongmok Whang",

year = "1991",

doi = "10.1016/S0957-4166(00)82151-5",

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volume = "2",

pages = "27--30",

journal = "Tetrahedron Asymmetry",

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T1 - Asymmetric induction in silyl nitronate cycloadditions to Oppolzer's chiral sultam derivatives

AU - Kim, Byeang Hyean

AU - Lee, Ju Young

AU - Kim, Kimoon

AU - Whang, Dongmok

PY - 1991

Y1 - 1991

N2 - Silyl nitronate cycloadditions to Oppolzer's chiral sultam derivatives, followed by the elimination of the silyl alcohols from the resulting N-silyloxyisoxazolidines, provide Δ2-isoxazolines in good stereoselectivity (ca. 89/11). The favored transition state is suggested in the light of the X-ray crystal structure of a major cycloadduct.

AB - Silyl nitronate cycloadditions to Oppolzer's chiral sultam derivatives, followed by the elimination of the silyl alcohols from the resulting N-silyloxyisoxazolidines, provide Δ2-isoxazolines in good stereoselectivity (ca. 89/11). The favored transition state is suggested in the light of the X-ray crystal structure of a major cycloadduct.

UR - https://www.scopus.com/pages/publications/0026036192

U2 - 10.1016/S0957-4166(00)82151-5

DO - 10.1016/S0957-4166(00)82151-5

M3 - Article

AN - SCOPUS:0026036192

SN - 0957-4166

VL - 2

SP - 27

EP - 30

JO - Tetrahedron Asymmetry

JF - Tetrahedron Asymmetry

IS - 1

ER -

Asymmetric induction in silyl nitronate cycloadditions to Oppolzer's chiral sultam derivatives

Abstract

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