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Aluminum containing periodic mesoporous organosilicas: Synthesis and etherification

  • Jin Won Kim
  • , Hyung Ik Lee
  • , Ji Man Kim
  • , Xingdong Yuan
  • , Jae Eui Yie
  • Ajou University
  • Fushun Petroleum University

Research output: Contribution to journalArticlepeer-review

Abstract

Aluminum has been successfully incorporated within the frameworks of periodic mesoporous organosilicas (Al-PMO) by co-condensation of bis(triethoxysilyl)ethane and dibutoxyaluminotriethoxysilane. The Al-PMO materials exhibit highly ordered 2-d hexagonal structures, high surface areas, and narrow pore size distribution in the mesoporous range. The Al-PMO catalysts result in excellent catalytic activity and selectivity for etherification reaction between 2-naphthol and ethanol, which is comparable with those of beta zeolite.

Original languageEnglish
Pages (from-to)665-668
Number of pages4
JournalStudies in Surface Science and Catalysis
Volume146
DOIs
StatePublished - 2003
Externally publishedYes

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