Acetamidinium bromoplumbate CH3C(NH2)2PbBr3 with 4H BaRuO3 structure

Hyun Jong Lee; Eunji Lee; Ji Hyun Cha; Duk Young Jung

doi:10.1002/bkcs.12660

Acetamidinium bromoplumbate CH₃C(NH₂)₂PbBr₃ with 4H BaRuO₃ structure

Hyun Jong Lee
, Eunji Lee
, Ji Hyun Cha
, Duk Young Jung

Department of Chemistry

Sungkyunkwan University
Chungnam National University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Acetamidinium bromoplumbate, denoted (ACA)PbBr₃, was synthesized from acetamidinium bromide and lead bromide in liquid medium under ambient atmosphere. The large radius of the acetamidinium group of (ACA)PbBr₃ accommodates the 4H BaRuO₃ structure, which has a hexagonal array of infinite face-shared and corner-shared [PbBr₆]⁴⁻ units. (ACA)PbBr₃ was characterized by single X-ray diffraction, chemical analyses, thermal analyses, ¹H NMR, and FT-IR spectroscopy.

Original language	English
Pages (from-to)	230-235
Number of pages	6
Journal	Bulletin of the Korean Chemical Society
Volume	44
Issue number	3
DOIs	https://doi.org/10.1002/bkcs.12660
State	Published - Mar 2023

Keywords

4H structure
acetamidinium bromide
BaRuO
hybrid perovskite
lead bromide

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10.1002/bkcs.12660

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@article{20c7ac9bf4bf4cf88714fba1a802c679,

title = "Acetamidinium bromoplumbate CH3C(NH2)2PbBr3 with 4H BaRuO3 structure",

abstract = "Acetamidinium bromoplumbate, denoted (ACA)PbBr3, was synthesized from acetamidinium bromide and lead bromide in liquid medium under ambient atmosphere. The large radius of the acetamidinium group of (ACA)PbBr3 accommodates the 4H BaRuO3 structure, which has a hexagonal array of infinite face-shared and corner-shared [PbBr6]4− units. (ACA)PbBr3 was characterized by single X-ray diffraction, chemical analyses, thermal analyses, 1H NMR, and FT-IR spectroscopy.",

keywords = "4H structure, acetamidinium bromide, BaRuO, hybrid perovskite, lead bromide",

author = "Lee, \{Hyun Jong\} and Eunji Lee and Cha, \{Ji Hyun\} and Jung, \{Duk Young\}",

note = "Publisher Copyright: {\textcopyright} 2022 Korean Chemical Society, Seoul \& Wiley-VCH GmbH.",

year = "2023",

month = mar,

doi = "10.1002/bkcs.12660",

language = "English",

volume = "44",

pages = "230--235",

journal = "Bulletin of the Korean Chemical Society",

issn = "0253-2964",

publisher = "Wiley-Blackwell",

number = "3",

}

TY - JOUR

T1 - Acetamidinium bromoplumbate CH3C(NH2)2PbBr3 with 4H BaRuO3 structure

AU - Lee, Hyun Jong

AU - Lee, Eunji

AU - Cha, Ji Hyun

AU - Jung, Duk Young

PY - 2023/3

Y1 - 2023/3

N2 - Acetamidinium bromoplumbate, denoted (ACA)PbBr3, was synthesized from acetamidinium bromide and lead bromide in liquid medium under ambient atmosphere. The large radius of the acetamidinium group of (ACA)PbBr3 accommodates the 4H BaRuO3 structure, which has a hexagonal array of infinite face-shared and corner-shared [PbBr6]4− units. (ACA)PbBr3 was characterized by single X-ray diffraction, chemical analyses, thermal analyses, 1H NMR, and FT-IR spectroscopy.

AB - Acetamidinium bromoplumbate, denoted (ACA)PbBr3, was synthesized from acetamidinium bromide and lead bromide in liquid medium under ambient atmosphere. The large radius of the acetamidinium group of (ACA)PbBr3 accommodates the 4H BaRuO3 structure, which has a hexagonal array of infinite face-shared and corner-shared [PbBr6]4− units. (ACA)PbBr3 was characterized by single X-ray diffraction, chemical analyses, thermal analyses, 1H NMR, and FT-IR spectroscopy.

KW - 4H structure

KW - acetamidinium bromide

KW - BaRuO

KW - hybrid perovskite

KW - lead bromide

UR - https://www.scopus.com/pages/publications/85144044983

U2 - 10.1002/bkcs.12660

DO - 10.1002/bkcs.12660

M3 - Article

AN - SCOPUS:85144044983

SN - 0253-2964

VL - 44

SP - 230

EP - 235

JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

IS - 3

ER -

Acetamidinium bromoplumbate CH₃C(NH₂)₂PbBr₃ with 4H BaRuO₃ structure

Abstract

Keywords

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