A new ionic liquid for a redox electrolyte of dye-sensitized solar cells

Research output: Contribution to journalArticlepeer-review

Abstract

A new ionic liquid, 1-vinyl-3-heptylimidazolium iodide (VHpII), was synthesized and applied as a redox electrolyte for dye-sensitized solar cells. The chemical structure of the synthesized VHpII was confirmed using 1H NMR. Thermogravimetric analysis showed that the VHpII was stable for thermal stress of up to 250°C. The energy conversion efficiencies of the VHpII-based dyesensitized solar cells were investigated in terms of the effect of a lithium iodide addition. A solar cell containing the redox couple of VHpII and iodine showed a conversion efficiency of 2.63% under 1 sun light intensity at AM 1.5. Adding 0.4 M LiI results in a conversion efficiency of 3.63%, which was an improvement of about 40%. The increased conversion efficiency was ascribed to an increase in external quantum efficiency.

Original languageEnglish
Pages (from-to)647-652
Number of pages6
JournalETRI Journal
Volume26
Issue number6
DOIs
StatePublished - Dec 2004
Externally publishedYes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 7 - Affordable and Clean Energy
    SDG 7 Affordable and Clean Energy

Keywords

  • 1-vinyl-3-heptylimidazolium iodide
  • Dye-sensitized solar cell
  • Ionic liquid
  • Molten salt
  • Redox electrolyte

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