A metal-organic framework as a chemical guide to control hydrogen desorption pathways of ammonia borane

Hyung Mo Jeong; Weon Ho Shin; Jung Hyo Park; Jung Hoon Choi; Jeung Ku Kang

doi:10.1039/c4nr01296h

A metal-organic framework as a chemical guide to control hydrogen desorption pathways of ammonia borane

Hyung Mo Jeong
, Weon Ho Shin
, Jung Hyo Park
, Jung Hoon Choi
, Jeung Ku Kang

Korea Advanced Institute of Science and Technology

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

We report that ammonia borane with a high uptake capacity for hydrogen can be encapsulated in a metal-organic framework (MOF) via capillary action, where the MOF functions as a chemical guide to control the hydrogen desorption pathways of ammonia borane by releasing only pure hydrogen, lowering its hydrogen desorption temperature, and suppressing its volumetric expansion during hydrogen desorption.

Original language	English
Pages (from-to)	6526-6530
Number of pages	5
Journal	Nanoscale
Volume	6
Issue number	12
DOIs	https://doi.org/10.1039/c4nr01296h
State	Published - 21 Jun 2014
Externally published	Yes

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10.1039/c4nr01296h

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title = "A metal-organic framework as a chemical guide to control hydrogen desorption pathways of ammonia borane",

abstract = "We report that ammonia borane with a high uptake capacity for hydrogen can be encapsulated in a metal-organic framework (MOF) via capillary action, where the MOF functions as a chemical guide to control the hydrogen desorption pathways of ammonia borane by releasing only pure hydrogen, lowering its hydrogen desorption temperature, and suppressing its volumetric expansion during hydrogen desorption.",

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year = "2014",

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doi = "10.1039/c4nr01296h",

language = "English",

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T1 - A metal-organic framework as a chemical guide to control hydrogen desorption pathways of ammonia borane

AU - Jeong, Hyung Mo

AU - Shin, Weon Ho

AU - Park, Jung Hyo

AU - Choi, Jung Hoon

AU - Kang, Jeung Ku

PY - 2014/6/21

Y1 - 2014/6/21

N2 - We report that ammonia borane with a high uptake capacity for hydrogen can be encapsulated in a metal-organic framework (MOF) via capillary action, where the MOF functions as a chemical guide to control the hydrogen desorption pathways of ammonia borane by releasing only pure hydrogen, lowering its hydrogen desorption temperature, and suppressing its volumetric expansion during hydrogen desorption.

AB - We report that ammonia borane with a high uptake capacity for hydrogen can be encapsulated in a metal-organic framework (MOF) via capillary action, where the MOF functions as a chemical guide to control the hydrogen desorption pathways of ammonia borane by releasing only pure hydrogen, lowering its hydrogen desorption temperature, and suppressing its volumetric expansion during hydrogen desorption.

UR - https://www.scopus.com/pages/publications/84901802401

U2 - 10.1039/c4nr01296h

DO - 10.1039/c4nr01296h

M3 - Article

AN - SCOPUS:84901802401

SN - 2040-3364

VL - 6

SP - 6526

EP - 6530

JO - Nanoscale

JF - Nanoscale

IS - 12

ER -

A metal-organic framework as a chemical guide to control hydrogen desorption pathways of ammonia borane

Abstract

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